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Water-Induced Micro-Hydrophobic Effect Regulates Benzene Methylation in Zeolite

 Date:2023/12/5 17:03:13 Views:Times

Micro-hydrophobic effects in benzene methylation over ZSM-5 were identified by using solid-state NMR experiments coupled with ultrahigh magic angle spinning technique and theoretical simulations. The micro-hydrophobic effects induced by the local water molecules in ZSM-5 channels can drive the benzene molecules towards to surface methoxy species (SMS) to form the active SMS-Benzene complex, which promotes benzene methylation.



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