^{原位NMR技术与催化反应机理}

     发展原位（in situ and operando）固体NMR技术，在宽温度（400 ℃）以及压力（50 bar）范围内，对气-固相以及液-固相催化反应过程进行NMR表征，结合快速采样方法，实现对催化剂结构与分子动态变化的快速跟踪与分析。

1.  Wang, X. M.; Qi, G. D.; Xu, J.; Li, B. J.; Wang, C.; Deng, F. NMR-Spectroscopic Evidence of Intermediate-Dependent Pathways for Acetic Acid Formation from Methane and Carbon Monoxide over a ZnZSM-5 Zeolite Catalyst. Angew. Chem. Int. Edit. 2012, 51, 3850-3853. 

2. Zhou, X.; Wang, C.; Chu, Y.; Xu, J.; Wang, Q.; Qi, G.; Zhao, X.; Feng, N.; Deng, F. Observation of an oxonium ion intermediate in ethanol dehydration to ethene on zeolite. Nat. Commun. 2019, 10, 1961.

3. Wang, C.; Zhao, X.; Hu, M.; Qi, G.; Wang, Q.; Li, S.; Xu, J.; Deng, F. Unraveling Hydrocarbon Pool Boosted Propane Aromatization on Gallium/ZSM-5 Zeolite by Solid-State Nuclear Magnetic Resonance Spectroscopy. Angew. Chem. Int. Edit. 2021, 60, 23630-23634.