超极化NMR技术与应用

     针对NMR本征灵敏度低的问题，开发仲氢诱导超极化技术（PHIP）以及动态核极化技术（DNP），打破热平衡下自旋核的波尔兹曼分布，获得NMR信号强度数个量级的提升，实现对催化材料结构的高灵敏表征；结合原位NMR技术，增强低含量反应物种（中间体、产物等）信号，实现对工况条件下催化反应的极化观测。

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2. W. Wang; Q. Wang; J. Xu; F. Deng, Understanding Heterogeneous Catalytic Hydrogenation by Parahydrogen-Induced Polarization NMR Spectroscopy. ACS Catal. 2023, 13, 3501-3519. 

3. W. Y. Wang; Q. M. Sun; Q. Wang; S. H. Li; J. Xu; F. Deng, Heterogeneous parahydrogen induced polarization on Rh-containing silicalite-1 zeolites: effect of the catalyst structure on signal enhancement. Catal. Sci. Technol. 2022, 12, 4442-4449.